MgO和Si上NbN超薄薄膜的生长研究

我们在单晶MgO(100)、Si(100)和SiOx/Si基片上成功生长了纳米厚度的超薄NbN薄膜,利用现代分析手段:X射线衍射(XRD)、透射电子显微镜(TEM)、原子力显微镜(AFM)等技术分析研究了所制备的超薄NbN薄膜的微观结构、厚度、表面界面情况等物理特性。研究表明,在MgO(100)基片上获得了外延生长的单晶NbN超薄薄膜,在Si(100)和SiOx/Si基片上获得的是多晶NbN超薄薄膜。厚度均约6nm左右。这些超薄薄膜的超导转变温度分别为:MgO上薄膜是14.46K,Si和SiOx上薄膜分别是8.74K和9.01K.     

A Comparative ESR Study on Blood and Tissue Nitric Oxide Concentration during Renal Ischemia-Reperfusion Injury

Electron paramagnetic resonance (EPR) spin trapping technology is a sensitive and unambiguous method for detection of nitric oxide (NO). Due to the short lifetime, NO must be trapped before EPR measurement. There are two EPR spin trapping techniques used currently, including the detections of EPR signals of diethyldithiocarbamate-iron-nitric oxide (DETC₂-Fe²⁺-NO) and nitrosyl hemoglobin (HbNO). In this study, we firstly investigated the kinetics of the EPR signal of DETC₂-Fe²⁺-NO in normal and ischemia-reperfused kidneys. In normal rat kidneys, the signal of DETC₂-Fe²⁺-NO was found at 5 min after the spin trappers Fe²⁺/DETC were administrated, the peak concentration was at 15 min and the period with relatively stable signal intensity was at the time range from 15 to 70 min. In the ischemia-reperfused rat kidneys, the signal of DETC₂-Fe²⁺-NO was increased at 30 min of ischemia and decreased at 60 min of ischemia after the occlusion of renal artery (corresponding to the time course of 60 and 90 min after Fe²⁺/DETC injection respectively). We then investigated the EPR signal of HbNO in blood. No characteristic HbNO signal was found in the rats of the sham control and 30 min of ischemia. An HbNO signal occurred in the rats exposed to 60 min of ischemia and it became pronounced with increased duration of reperfusion. The signal intensity reached a plateau at 150 min of reperfusion. The results suggest that the DETC₂-Fe²⁺-NO signal can be only suitable for the NO measurement in the short-term ischemia-reperfusion model, whereas the HbNO signal can be applied to represent NO in the relatively long-term ischemia-reperfusion model. In addition, N^G-nitro-L-arginine (L-NAME) and allopurinol were used to identify the source of NO. By detecting the HbNO signal, we demonstrated that the activation of xanthine oxidase is an important source of NO formation at the long-term period of ischemia and reperfusion. Authors' address: Jiangang Shen, School of Chinese Medicine, University of Hong Kong, 10 Sassoon Road, Hong Kong SAR, China     

Semiconductor quantum dots in high magnetic fields

We review and extend the composite fermion theory for semiconductor quantum dots in high magnetic fields. The mean-field model of composite fermions is unsatisfactory for the qualitative physics at high angular momenta. Extensive numerical calculations demonstrate that the microscopic CF theory, which incorporates interactions between composite fermions, provides an excellent qualitative and quantitative account of the quantum dot ground state down to the largest angular momenta studied, and allows systematic improvements by inclusion of mixing between composite fermion Landau levels (called Λ levels).     

转动分辨的H2+ (X2Σ+g , v+=0-18)真空紫外脉冲场电离光电子谱

测量了氢气离子转动分辨的真空紫外脉冲场电离光电子谱．涵盖了15.30?18.09 eV能量范围内的H2+(X2§+g , v+=0?18,N+=0?5)?H2(X1§+g , v00=0, J00=0?4)的电离跃迁． 通过基于Buckingham-Orr-Sichel(BOS)模型的光谱拟合和对氢气离子振动带H2+(X2§+g ,v+=0?18)的转动光谱的分析, 发现实验上只观察到对应于￠N=N+-J00=0,§2的转动跃迁． 振动量子数v+ 越高，￠N=0的转动跃迁越占主导地位， 而转动谱线强度受邻     

Complete suppression of metastable phase and significant enhancement of magnetic properties of B-rich PrFeB nanocomposites prepared by devitrifying amorphous ribbons

The effect of refractory element addition on phase transformation, crystallization behavior and magnetic properties of Pr_8.5Fe_81.5B₁₀ (addition-free) and Pr_8.5Fe_81.5M₂B₁₀ (M=V, Cr, Nb, Zr, Ti) ribbons has been investigated. The annealed addition-free ribbon as well as the samples with V or Cr additions are mainly composed of the metastable Pr₂Fe₂₃B₃ phase, whereas annealed ribbons with Nb, Zr or Ti additions primarily consist of Pr₂Fe₁₄B and a minor amount of Fe₃B/boride. The complete suppression of the metastable Pr₂Fe₂₃B₃ phase due to Nb, Zr or Ti additions leads to a significant enhancement of the magnetic properties. For example, the remanence, the coercivity and the energy product are remarkably increased from 2.5 kG, 0.4 kOe and 0.2 MG Oe for the addition-free material to 9.2 kG, 4.7 kOe and 7.6 MG Oe for the specimens with Nb addition. The successful elimination of the metastable Pr₂Fe₂₃B₃ phase is believed to profit from two factors: (a) Nb, Zr or Ti atoms substitute the Pr site, comparatively increase the Pr content, and thus inhibit the nucleation of Pr-lean Pr₂Fe₂₃B₃ phases, and (b) the formation of Nb, Zr, or Ti borides consumes some part of B, which hinders the generation of the B-rich Pr₂Fe₂₃B₃ phase.     

Effect of Ce2(SO4)3 on structure and properties of Ni-Co/Al2O3 composite coating deposited by pulse reverse current method

Composite coating of Ni-Co/Al₂O₃ was deposited in Ce₂(SO₄)₃ containing electrolyte by pulse reverse current (PRC) method. The effect of Ce₂(SO₄)₃ in electrolyte on morphology, microstructure, composition, micro-hardness and residual macrostress of composite coating was investigated. The results indicates that with addition of Ce₂(SO₄)₃ in electrolyte, the composite coating becomes uniform, compact and possesses finer grains, the composite content of Al₂O₃ is enhanced, the micro-hardness of composite coating is improved, while the residual macrostress is decreased.     

Surface status and size influences of nickel nanoparticles on sulfur compound adsorption

Metallic nickel nanoparticles were incorporated on mesoporous silica to remove sulfur compounds in diesel selectively. In the first method, nickel nanoparticles were formed on mesoporous silica SBA-15 by impregnation and subsequent reduction of nickel nitrate. The sulfur adsorption capacity was strongly dependent on the nickel loading and the average nickel particle size. In the second method, nickel nanoparticles were synthesized in solution in the presence of a capping agent and then incorporated in mesoporous silica MCF by sonication. Although these particles maintain their sizes on the MCF surface after heat treatment, capping agent remaining on the Ni particle surface might interfere the adsorption of sulfur compounds.     

Efficient generation of a photon pair in a bulk periodically poled potassium titanyl phosphate

In this report, we demonstrate the efficient generation of collinearly propagating photon pairs in a bulk periodically poled potassium titanyl phosphate pumped by a cw laser. The detected coincidence counts are more than 7400/s with 3.58 mW pump power in a Hanbury-Brown-Twiss-type experiment. The estimated photon pair production rate is about 0.73 MHz/mW. This is very promising for some applications, such as quantum key distribution, proof of the Bell-inequality, preparation of single photon states in broadband wave packets, Franson-type interference and so on.     

Effects of hydrogen flux on the properties of Al-doped ZnO films sputtered in Ar + H2 ambient at low temperature

Al-doped ZnO (AZO) transparent conductive thin films were grown by magnetron sputtering with AZO (98 wt.% ZnO, 2 wt.% Al₂O₃) ceramic target in Ar + H₂ ambient at a relatively low temperature of 100 °C. To investigate the dependence of crystalline and properties of as-grown AZO films on the H₂-flux, X-ray diffraction (XRD), X-ray photoemission spectrometer (XPS), Hall and transmittance spectra measurements were employed to analyze the AZO samples deposited with different H₂-flux. The results indicate that H₂-flux has a considerable influence on the transparent conductive properties of AZO films. The resistivity of 4.15 × 10⁻⁴ Ω cm and the average transmittance of more than 94% in the visible range were obtained with the optimal H₂-flux of 1.0 sccm. Such a low temperature growing method present here may be especially useful for some low-melting point photoelectric devices and substrates.     

Electrodynamic Analysis of Dissipative Electromagnetic Materials Based on Fractional Derivative

The generalized Lagrangian is defined in a dissipative electromagnetic medium on the basis of the combination of dynamical analysis and fractional derivative. Lorentz medium models are obtained by formulating relevant Euler-Lagrange equations. The invariance is obtained subsequently by investigating the invariance of time variation in the system, and then the relation between the related Hamiltonian and electromagnetic energy density is investigated. Canonical equations are obtained eventually. The electrodynamic interpretation on dissipative electromagnetic systems is revealed.